Then i dont see why it wouldnt work. But as I said before I dont run Windows xp so I have no way to test that system. What happens when you try to run it? Does it load? Does the Original MAME64 work from there site?
I just did some checking and since MAME is compiled in GCC now it will not run in Windows Xp you will have to upgrade to windows 7 or higher if you want to use it.