I attached a couple of pictures. As you can see in 3.jpg, there are no games listed on the right hand side. Again, i have done nothing but follow the steps in this guide, so I don't know if I need to configure more?!
my rom path is not the default folder (hence the different folder names)
also my mame.ini file isn't where you listed (HyperSpin\Databases), only .xml files exist here
my mame.ini file is (emulators\mame\v0.152\) folder.
below is the first few lines of my mame.ini (which should be correct):
#
# CORE CONFIGURATION OPTIONS
#
readconfig 1
writeconfig 0
#
# CORE SEARCH PATH OPTIONS
#
rompath e:\pleasuredome\mame roms
hashpath hash
samplepath samples
artpath artwork
ctrlrpath ctrlr
inipath .;ini
fontpath .
cheatpath cheat
crosshairpath crosshair